Champions League holders Liverpool will face Napoli in the group stage for a second season running after the two sides were drawn together in Monaco.
Jurgen Klopp’s men edged past the Serie A club en route to winning the competition last season. Liverpool will also play FC Salzburg and Belgian side Genk in Group E.
Tottenham, who the Reds beat in last season’s final, have been drawn alongside Bayern Munich in Group B, Greek side Olympiakos and Red Star Belgrade.
Europa League champions Chelsea are up against Ajax, who beat the likes of Real Madrid and Juventus last season. Frank Lampard’s men will also play Valencia and French side Lille in Group H.
Meanwhile, Premier League champions Manchester City are in Group C and will face Shakhtar Donetsk, Dinamo Zagreb and Atalanta.
The ceremony also saw Liverpool defender Virgil van Dijk scoop up the men’s Player of the Year award – beating Cristiano Ronaldo and Lionel Messi to the prize.